I was actually just asking if you were putting in R-134a or Freon, since Freon is a brand name for R-12. I hadn't actually realized they branded their other refrigerants under the same name.
As for the article, I agree with most of it, but I think the best replacement for R-134a is still debatable. The one suggested (HFO-1234yf) seems to have potential if the claims they made are true.
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Originally Posted by
Vadim
R152a sounds great, except for it's combustible, and poisonous when burns. This is why CO2 is also being considered. Problem with CO2 is, it requires to be at over 1k psi, which would put a great amount of stress on the lines.
I dug up my paper on the subject (I wrote it last fall). Here is the section regarding R-152a. It is more environmentally friendly and exhibits better performance, but is flammable and less miscible. Because of the latter, it seems unlikely that it will take the place of R-134a in automobiles, but will become more common in general industry, where safety can be better regulated.
HFC-134a is widely accepted because of its low risk factor (rated A1), decent performance, and zero ODP. However, it does have a relatively high GWP of 1320. The replacement suggested here, HFC-152a, not only outperforms HFC-134a, but also boasts a largely reduced GWP of only 140 and a general increase in COP of around 2%. Due to its flammability, however, its future as an HFC-134a replacement is questionable (rated A2 on the ASHRAE scale). Furthermore, the increased hydrogen content of HFC-152a means it may be even worse than HFC-134a when it comes to accepting traditional oils for component lubrication (Devotta S. , 1995)
Pure hydrocarbon refrigerants (HC's as opposed to HFC, CFC, HCFC, etc.) are best for the environment (like propane), but pose obvious safety dangers to humans. Particularly in systems with pressures lower than the ambient air, there is a danger of oxygen leaking in and mixing with the refrigerant creating a highly explosive mixture. If that safety issue can be overcome, R-134a will most likely be replaced by a hydrocarbon refrigerant (at least as another intermediate). R-134a was never meant to be a permanent replacement for Freon.
As for CO2, you're right about high pressure systems. It also seems an unlikely solution if you consider the carbon footprint planning view of the future.
Oh, it looks like I got a little carried away there.