here's a pic of my TB: there's only one vac nipple on the bottom, and one for the FPR. I capped that because I'm running all my other vac off the vac manifold. You can use that one, and if you're gonna use T's, that's the one I'd use. If you have another vac nipple down there going to a sensor, that sounds like a DE TB with the EGR stuff still on there. If you have removed the EGR stuff, you can remove that sensor and use the port. Snap a pic of it if you can... The other two ports off the TB are coolant, I assume you knew that.
MY TB:
The Vac manifold:
The large hose obviously goes to the brake booster and the other ports are all blank 1/8npt wells, and you drill out however many you're going to use. I am only using 4, but there are 6 blanks. I have them for my boost gauge, zeitronix map sensor, bov, and boost controller. It cleaned up my engine bay and hoses a lot.
Edit: the small nipple on your bov is for a boost reference. It adds responsiveness to the bov or can simply be a vent for the air that the diaphragm moves. if you search around there are threads about using it as a boost reference, but I don't think it matters one way or the other.